Hydrochloric Acid → Tri-n-decylcarbinol

HRID 2583

反応式

HRID 2583 の反応式
Br[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11].[Mg].C(=O)([O:17][CH2:18][CH3:19])OCC.Cl>C(OCC)C>[CH2:2]([C:18]([CH2:19][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10])([CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[OH:17])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11]

参加物

6

反応物 4

HCID 313Hydrochloric AcidHCID 7766Diethyl CarbonateHCID 81731-BromodecaneHCID 5462224Magnesium

生成物 1

HCID 19690419Tri-n-decylcarbinol

試薬・触媒・溶媒 1

HCID 3283Diethyl Ether溶媒2 回

反応条件

温度
30 °C

実験手順

Three moles of 1-bromodecane was slowly added to 3 moles of magnesium turnings in 0.6 liters of anhydrous ethyl ether (nitrogen atmosphere). One mole of diethyl carbonate in 0.151 anhydrous ethyl ether was slowly added to the mixture. After stirring for one hour at 30° C., the mixture was slowly poured into 1.8 liters of a cold 10% HCl solution. The organic layer was dried with magnesium sulfate and the ethyl ether evaporated off to give tri-n-decylcarbinol.

後処理

  1. dry with materialThe organic layer was dried with magnesium sulfate
  2. customthe ethyl ether evaporated off

出典と根拠

ORDレコード
ord-5831ca84c85c45188e821732a2150987
出典データセット
uspto-grants-1998_03
特許番号
US05728907

関連ノート

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