Hydrochloric Acid → Tri-n-decylmethylchloride

HRID 2584

反応式

HRID 2584 の反応式
[CH2:1]([C:11]([CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH3:32])([CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])O)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10].[Cl-:33].[Ca+2].[Cl-].Cl>C(Cl)Cl>[CH2:1]([C:11]([Cl:33])([CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH3:32])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10]

参加物

5

反応物 3

HCID 313Hydrochloric AcidHCID 5284359Calcium ChlorideHCID 19690419Tri-n-decylcarbinol

生成物 1

HCID 19690416Tri-n-decylmethylchloride収率 90%

試薬・触媒・溶媒 1

HCID 6344Dichloromethane溶媒

実験手順

One mole of tri-n-decylcarbinol was added to a mixture of 0.2 liters of methylene chloride and 0.32 moles calcium chloride. Approximately 1.5 moles of HCl gas was slowly bubbled through the solution. The product mixture is then washed with 1 liter of a 10% sodium carbonate solution. The organic layer is dried with magnesium sulfate and the methylene chloride evaporated off to give a 90% yield of tri-n-decylmethylchloride.

後処理

  1. washThe product mixture is then washed with 1 liter of a 10% sodium carbonate solution
  2. dry with materialThe organic layer is dried with magnesium sulfate
  3. customthe methylene chloride evaporated off

出典と根拠

ORDレコード
ord-43db573a1030471e9bdddb88415b043e
出典データセット
uspto-grants-1998_03
特許番号
US05728907

関連ノート

読み込み中…