化工社化工社 化学情報印刷レポート · 研究参考用
5-Norbornene-2-carboxylic acid → Bicyclo[2.2.1]heptane-2-carboxylic acid
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 5-Norbornene-2-carboxylic acid | HCID 78949 | — |
| 溶媒 | HCID 178418390 | HCID 178418390 | — |
| 生成物 | Bicyclo[2.2.1]heptane-2-carboxylic acid | HCID 79113 | 100.8% |
反応手順
38.8 g (269 mmol) of crude 5-norbornene-2-carboxylic acid was dissolved in 740 ml of solmix, 1.92 g of 5% palladium-carbon powder was added and the mixture was stirred for 17.5 hours under an atmosphere of hydrogen. The catalyst was filtered off, the solvent was distilled away, and 38.0 g of crude 2-norbornanecarboxylic acid was obtained. Crude yield: 100%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05266728 |
| 出典データセット | uspto-grants-1993_11 |
| ORD ID | ord-a007d9d920d5419eb401b6a7ad62a729 |
| 出典メモ | uspto-grants-1993_11 |