化工社化工社 化学情報印刷レポート · 研究参考用
5-Norbornene-2-carboxylic acid → Bicyclo[2.2.1]heptane-2-carboxylic acid
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 5-Norbornene-2-carboxylic acid | HCID 78949 | — |
| 触媒 | HCID 178418390 | HCID 178418390 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | Bicyclo[2.2.1]heptane-2-carboxylic acid | HCID 79113 | 94% |
反応手順
15.7 g (110 mmol) of crude 5-norbornene-2-carboxylic acid was dissolved in 300 ml of ethanol, 1.55 g of 5% palladium-carbon powder was added, and the mixture was stirred under an atmosphere of hydrogen for 24 hours. After the catalyst was filtered off, the solvent was distilled off, and 14.5 g of crude 2-norbornanecarboxylic acid was obtained. Crude yield: 94%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05266728 |
| 出典データセット | uspto-grants-1993_11 |
| ORD ID | ord-450580ae0ff94758a4f9e307b836054b |
| 出典メモ | uspto-grants-1993_11 |