Sulfuric Acid → Diurea silicate

HRID 258525

反応式

HRID 258525 の反応式
S(=O)(=O)(O)O.[OH:6][Si:7]([OH:9])=[O:8].[NH2:10][C:11]([NH2:13])=[O:12]>>[Si:7]([OH:12])([OH:9])([OH:6])[OH:8].[NH2:10][C:11]([NH2:13])=[O:12].[NH2:10][C:11]([NH2:13])=[O:12]

参加物

4

反応物 3

HCID 1118Sulfuric AcidHCID 1176UreaHCID 14768Metasilicic acid

生成物 1

HCID 86734905Diurea silicate

実験手順

Clay is reacted with sulfuric acid, thereby producing metasilicic acid, which is recovered by filtration. About one mol of said metasilicic acid is mixed with 2 mols of urea, heated to 90° to 150° C. for 20 to 30 minutes, thereby producing white granules of diurea silicate. The said diurea silicate is added to an aqueous solution of hexamethylene tetramine in the ratio of 1:1.5 mols, heated to 70° to 110° C. for 20 to 90 minutes, thereby producing a clear thick solution of poly (formaldehyde diurea silicate) resin, and upon further heating, a white resin is produced. The said white resin is soluble in acetic acid and produces a clear solution; the unreacted silicic acid is precipitated. The solution of poly (formaldehyde diurea silicate) resin forms a clear tough coating on wood.

後処理

  1. filtrationproducing metasilicic acid, which is recovered by filtration
  2. temperatureheated to 90° to 150° C. for 20 to 30 minutes

出典と根拠

ORDレコード
ord-5644ac4ffb6c4a22adbacbe670db9341
出典データセット
uspto-grants-1977_07
特許番号
US04033935

関連ノート

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