Hydrazine Sulfate → HCID 178433316、化合物

HRID 258744

反応式

HRID 258744 の反応式
[ClH:1].Cl.Cl.O[N:5]([CH2:19][CH2:20][S:21][CH2:22][C:23]1[NH:27][CH:26]=[N:25][C:24]=1[CH3:28])[C:6]([NH2:18])=[N:7][CH2:8][CH2:9][S:10][CH2:11][C:12]1[NH:16][CH:15]=[N:14][C:13]=1[CH3:17].S(O)(O)(=O)=O.[NH2:34]N.C(=O)([O-])O.[K+]>CN(C)C=O>[ClH:1].[ClH:1].[ClH:1].[NH2:34][NH:18][C:6]([NH:5][CH2:19][CH2:20][S:21][CH2:22][C:23]1[NH:27][CH:26]=[N:25][C:24]=1[CH3:28])=[N:7][CH2:8][CH2:9][S:10][CH2:11][C:12]1[NH:16][CH:15]=[N:14][C:13]=1[CH3:17]

参加物

5

反応物 3

HCID 24842Hydrazine SulfateHCID 516893Potassium BicarbonateHCID 178433318HCID 178433318、化合物

生成物 1

HCID 178433316HCID 178433316、化合物

試薬・触媒・溶媒 1

HCID 6228Dimethylformamide溶媒

実験手順

A mixture of the isothiourea trihydrochloride from Example 2 (ii) (5.1 g), hydrazine sulphate (1.6 g), potassium hydrogen carbonate (7.0 g) and anhydrous dimethyl formamide (60 ml) was stirred at 70° for 3 hours. Following cooling and filtration the filtrate containing the free base was treated with an excess of ethanolic hydrogen chloride to give the title compound.

後処理

  1. temperatureFollowing cooling
  2. filtrationfiltration the filtrate
  3. additioncontaining the free base
  4. additionwas treated with an excess of ethanolic hydrogen chloride

出典と根拠

ORDレコード
ord-bded5c2ab36842c086cd8244c474c63f
出典データセット
uspto-grants-1977_07
特許番号
US04034101

関連ノート

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