Hydroquinone → Propane, 1,3-bis(ethenylsulfonyl)-
反応式
Cl[CH2:2][CH2:3][S:4]([CH2:7][CH2:8][CH2:9][S:10]([CH2:13][CH2:14]Cl)(=[O:12])=[O:11])(=[O:6])=[O:5].C1(C=CC(O)=CC=1)O.C(N(CC)CC)C>C(OCC)(=O)C>[CH:13]([S:10]([CH2:9][CH2:8][CH2:7][S:4]([CH:3]=[CH2:2])(=[O:6])=[O:5])(=[O:12])=[O:11])=[CH2:14]参加物
5
反応条件
- 温度
- 25 °C
実験手順
1,3-Bis(2-chloroethylsulfonyl)propane (74.5 g., 0.249 mole) was suspended in 2,300 ml. of ethyl acetate containing 0.12 g. hydroquinone. Triethylamine (50.7 g., 0.50 mole) was dropped in with stirring, within 10 minutes at 25° C. The resulting mixture was stirred at 25° C. for 20 hours. The amine salt was filtered off and the ethyl acetate solution evaporated at 30° C. The tan-colored solid was washed with water, then recrystallized from ethanol; yield 32.8 g. (59 percent); m.p. 60°-63° C.
後処理
- stirringThe resulting mixture was stirred at 25° C. for 20 hours
- filtrationThe amine salt was filtered off
- customthe ethyl acetate solution evaporated at 30° C
- washThe tan-colored solid was washed with water
- customrecrystallized from ethanol
出典と根拠
- ORDレコード
- ord-05f74795aa924f489d8c2fbce9c07bfb
- 出典データセット
- uspto-grants-1977_07
- 特許番号
- USRE029305
反応ノート
読み込み中…