関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Hydrochloric Acid | HCID 313 | — |
| 反応物 | Diethyl Carbonate | HCID 7766 | — |
| 反応物 | HCID 178418320 | HCID 178418320 | — |
| 反応物 | HCID 178418384 | HCID 178418384 | — |
| 溶媒 | Diethyl Ether | HCID 3283 | — |
| 生成物 | Di-n-decyl-n-tetradecylcarbinol | HCID 19690406 | — |
反応手順
Decylmagnesium bromide (0.66 mole) in ethyl ether is slowly added to 0.33 moles of diethylcarbonate in 100 ml ethyl ether and stirred for one hour at 30° C. (nitrogen atmosphere). Tetradecylmagnesium bromide (0.33 moles) is slowly added to the solution and stirred for one hour at 30° C. The mixture is then slowly poured into 600 ml of a cold 10% HCl solution. The organic layer is dried with magnesium sulfate and the ethyl ether evaporated off to give di-n-decyl-n-tetradecylcarbinol.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US05728907 |
|---|
| 出典データセット | uspto-grants-1998_03 |
|---|
| ORD ID | ord-108d826840d345cdb28e811cd9a5ff6a |
|---|
| 出典メモ | uspto-grants-1998_03 |
|---|
