化工社化工社 化学情報印刷レポート · 研究参考用
N,N-Dimethylbenzylamine → HCID 21425139、化合物
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | N,N-Dimethylbenzylamine | HCID 7681 | — |
| 反応物 | Trichloropentylsilane | HCID 7885 | — |
| 反応物 | alpha-Bromoethyltriethoxysilane | HCID 21425138 | — |
| 溶媒 | Methyl Ethyl Ketone | HCID 6569 | — |
| 生成物 | HCID 21425139 | HCID 21425139 | — |
反応手順
In a manner like that used for the preparation of alpha-bromoethyltriethoxysilane, alpha-bromoamyltriethoxysilane is prepared in two steps from amyltrichlorosilane (commercially available). One-quarter mole of alpha-bromoamyltriethoxysilane (78.5g) is refluxed for 12 hours with 0.25 moles (33.75g) of benzyldimethylamine in 125 ml. of 2-butanone. The product, alpha-(benzyldimethylammonio)ethyltriethoxysilane bromide is isolated by removing the solvent under vacuum.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04035411 |
| 出典データセット | uspto-grants-1977_07 |
| ORD ID | ord-c4e838e1b7d3491287275096ae3d8e91 |
| 出典メモ | uspto-grants-1977_07 |