1-Dodecene → 2-Methyl-7-octadecene

反応式

[CH2:1]=[CH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10]CC.[CH3:13][CH:14]([CH3:21])[CH2:15][CH2:16][CH2:17][CH2:18][CH:19]=[CH2:20]>>[CH3:13][CH:14]([CH2:15][CH2:16][CH2:17][CH2:18][CH:19]=[CH:20][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10])[CH3:21]

参加物

反応物 2

HCID 81831-Dodecene

HCID 5187147-Methyl-1-octene

生成物 1

HCID 1419952-Methyl-7-octadecene

実験手順

In the manner described in Example 4, 110 g. (0.66 mole) of 1-dodecene and 16 g. (0.13 mole) of 7-methyl-1-octene are reacted at a reaction temperature of 100° C. After 21/2 hours and a throughput of 200 ml. of olefin mixture per hour, 8.7% by weight of 2-methyl-7-octadecene is obtained. The extractor contains in this case 26.6 g. of the catalyst described in Example 4.

後処理

custom2 hours

出典と根拠

ORDレコード: ord-6a82fcb7e3a34b56a90cd30dd5d75939
出典データセット: uspto-grants-1977_07
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04036858

反応ノート

読み込み中…