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Chlorotrimethylsilane → 3,3'-Bis(trimethylsiloxy)-4,4'-bis(trimethylsilylamino)biphenyl
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Chlorotrimethylsilane | HCID 6397 | — |
| 反応物 | Dianisidine | HCID 8411 | — |
| 反応物 | 3,3'-Dihydroxybenzidine | HCID 16918 | — |
| 反応物 | Hydrogen iodide | HCID 24841 | — |
| 溶媒 | Tetrahydrofuran | HCID 8028 | — |
| 溶媒 | Triethylamine | HCID 8471 | — |
| 生成物 | 3,3'-Bis(trimethylsiloxy)-4,4'-bis(trimethylsilylamino)biphenyl | HCID 11156392 | — |
反応手順
0.540 g of 3,3'-dihydroxy-4,4'-diaminobiphenyl (synthesized from 3,3'-dimethoxy-4,4'-diaminobiphenyl using hydrogen iodide by the known method) and 1.52 g of triethylamine were dissolved in 16 mL of dry tetrahydrofuran. 1.63 g of trimethylchlorosilane was then added dropwise followed by heating under reflux for 72 hours. Operating in an argon atmosphere, the salt was filtered off and the solvent, etc., was removed under reduced pressure to yield 3,3'-bis(trimethylsiloxy)-4,4'-bis(trimethylsilylamino)biphenyl.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05527862 |
| 出典データセット | uspto-grants-1996_06 |
| ORD ID | ord-e83fd7405009452894335135ffaf77bf |
| 出典メモ | uspto-grants-1996_06 |