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1,5-Hexadiene → Bis{(2-phenylpropyl)dichlorosilyl}hexane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1,5-Hexadiene | HCID 11598 | — |
| 反応物 | 3-Phenyl-1,1-dichloro-1-silabutane | HCID 123324342 | — |
| 触媒 | Chloroplatinic acid | HCID 61859 | — |
| 溶媒 | Isopropanol | HCID 3776 | — |
| 生成物 | Bis{(2-phenylpropyl)dichlorosilyl}hexane | HCID 22401800 | 66% |
反応手順
In the same apparatus and procedures as EXAMPLE 1, 21.3 g (0.097 mole) of 3-(phenyl)-1,1-dichloro-1-silabutane and 100 μl of 1% chloroplatinic acid solution in isopropanol were placed and then 3.2 g (0.039 mole) of 1,5-hexadiene was added dropwise for 5 min. The solution was reacted for 15 hours at reflux under the dry nitrogen atmosphere. Vacuum distillation gave 13.4 g (185°-187° C./0.03 mmHg) of bis{(2-phenylpropyl)dichlorosilyl}hexane in 66.0% yield.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05527934 |
| 出典データセット | uspto-grants-1996_06 |
| ORD ID | ord-c15b152b25914a5b80fd96089064b04b |
| 出典メモ | uspto-grants-1996_06 |