3-Heptanoylindole → 4-Methoxybenzyl 4-[3-(3-heptyl-2-decenoyl)-1-indolyl]butyrate
反応式
[CH2:1]([C:8]([CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH3:27])=[CH:9][C:10]([C:12]1[C:20]2[C:15](=[CH:16][CH:17]=[CH:18][CH:19]=2)[NH:14][CH:13]=1)=[O:11])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH3:7].C(C1C2C(=CC=CC=2)NC=1)(=O)CCCCCC.Br[CH2:46][CH2:47][CH2:48][C:49]([O:51][CH2:52][C:53]1[CH:58]=[CH:57][C:56]([O:59][CH3:60])=[CH:55][CH:54]=1)=[O:50]>>[CH2:21]([C:8]([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH3:7])=[CH:9][C:10]([C:12]1[C:20]2[C:15](=[CH:16][CH:17]=[CH:18][CH:19]=2)[N:14]([CH2:46][CH2:47][CH2:48][C:49]([O:51][CH2:52][C:53]2[CH:58]=[CH:57][C:56]([O:59][CH3:60])=[CH:55][CH:54]=2)=[O:50])[CH:13]=1)=[O:11])[CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH3:27]参加物
4
実験手順
The procedure of Ex. 1 was repeated except that 3-(3-heptyl-2-decenoyl)indole obtained in Pre. Ex. 26 was used in place of 3-heptanoylindole, and 4-methoxybenzyl 4-bromobutyrate was used in place of 4-bromobutyrate to give 4-methoxybenzyl 4-[3-(3-heptyl-2-decenoyl)-1-indolyl]butyrate as an oil.
後処理
- customobtained in Pre