関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Benzaldehyde | HCID 240 | — |
| 反応物 | Methylhydrazine | HCID 6061 | — |
| 反応物 | 2-(Bis(methylsulfanyl)methylidene)propanedinitrile | HCID 99229 | — |
| 溶媒 | 2-Methoxyethanol | HCID 8019 | — |
| 生成物 | Benzaldehyde N-methyl-N-(2,2-dicyano-1-methylmercaptoethenyl) hydrazone | HCID 54443969 | — |
反応手順
Methyl hydrazine (4.2 g) was added slowly to benzaldehyde (9.4 ml) in 2-methoxyethanol (15 ml) causing the solution to boil. The solution was heated under reflux for 20 minutes and was then added to a solution of bis(methylmercapto)methylenemalononitrile (15.6 g) in 2-methoxyethanol (75 ml). The solution was heated under reflux for 6 hours and was then cooled to 0° C. to precipitate benzaldehyde N-methyl-N-(2,2-dicyano-1-methylmercaptoethenyl) hydrazone (5.6 g), m.p. 159°-160° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04163846 |
|---|
| 出典データセット | uspto-grants-1979_08 |
|---|
| ORD ID | ord-af57ceba72d4402a894e010ee4dbe617 |
|---|
| 出典メモ | uspto-grants-1979_08 |
|---|
