関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Diethyl Ether | HCID 3283 | — |
| 反応物 | Carbon Disulfide | HCID 6348 | — |
| 反応物 | 6-Ethylpyridin-2-amine | HCID 89021 | — |
| 溶媒 | Acetonitrile | HCID 6342 | — |
| 溶媒 | Triethylamine | HCID 8471 | — |
| 生成物 | Triethylammonium 6-ethylpyrid-2-yldithiocarbamate | HCID 20393066 | — |
反応手順
A solution of carbon disulphide (17.5 cc) in anhydrous acetonitrile (19.5 cc) is added to a solution of 2-amino-6-ethylpyridine (27.0 g) in anhydrous triethylamine (60 cc) at a temperature of 25° C. After 20 hours stirring at 20° C., anhydous diethyl ether (250 cc) is added. After cooling for 1 hour at 2° C., the resulting crystals are filtered off, washed three times with anhydrous diethyl ether (240 cc) and dried under reduced pressure (20 mm.Hg) at 20° C. to give triethylammonium (6-ethylpyrid-2-yl)dithiocarbamate (42.0 g) melting at 75° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04164579 |
|---|
| 出典データセット | uspto-grants-1979_08 |
|---|
| ORD ID | ord-e4ddccb2a9874fb6a59f5aab1ef95064 |
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| 出典メモ | uspto-grants-1979_08 |
|---|
