Acetic Acid → HCID 21317597、化合物

HRID 263002ノート

反応式

HRID 263002 の反応式
Cl[CH2:2][CH2:3][S:4][CH:5]([CH2:17][CH2:18][CH2:19][CH:20]([O:26]C(=O)C)[CH2:21][CH2:22][CH2:23][CH2:24][CH3:25])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][C:12]([O:14]CC)=[O:13].OO.[OH2:32].C(O)(=[O:35])C>CCOCC>[CH:3]([S:4]([CH:5]([CH2:17][CH2:18][CH2:19][CH:20]([OH:26])[CH2:21][CH2:22][CH2:23][CH2:24][CH3:25])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][C:12]([OH:14])=[O:13])(=[O:35])=[O:32])=[CH2:2]

参加物

6

反応物 4

HCID 176Acetic AcidHCID 784Hydrogen PeroxideHCID 962WaterHCID 21317532Ethyl 8-(2-chloroethylthio)-12-acetoxyheptadecanoate

生成物 1

HCID 21317597HCID 21317597、化合物

試薬・触媒・溶媒 1

HCID 3283Diethyl Ether溶媒

実験手順

A solution of ethyl 8-(2-chloroethylthio)-12-acetoxyheptadecanoate (45.1 g., 0.1 mole) and 30% aqueous hydrogen peroxide (50 ml.) in acetic acid (225 ml.) is allowed to stand 20 hours at 25° C. The solution is diluted with 600 ml. of water. The oily product is taken up in ether, washed with dilute sodium bicarbonate solution and four portions of water and dried over sodium sulfate. Evaporation of the ether in vacuo leaves the title compound as a light yellow viscous oil.

後処理

  1. additionThe solution is diluted with 600 ml
  2. washwashed with dilute sodium bicarbonate solution and four portions of water
  3. dry with materialdried over sodium sulfate
  4. customEvaporation of the ether in vacuo

出典と根拠

ORDレコード
ord-d9a92703651b41ab9b19593138d127a2
出典データセット
uspto-grants-1979_05
特許番号
US04155908

反応ノート

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