関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Water | HCID 962 | — |
| 反応物 | 2-Cyclohexen-1-OL | HCID 13198 | — |
| 反応物 | Acetic acid, cyclopent-2-en-1-yl ester | HCID 140735 | — |
| 触媒 | Tetrabutylammonium hydrogen sulfate | HCID 94433 | — |
| 溶媒 | Acetone | HCID 180 | — |
| 生成物 | HCID 21318237 | HCID 21318237 | — |
反応手順
A two-phase reaction mixture containing 2-cyclopentenyl acetate (0.30 g, 2.4 millimols), 2-cyclohexenol (0.50 g, 5.1 millimols), tetrabutylammonium hydrogen sulfate (0.020 g, 0.06 millimols), and water (0.25 g, 13.9 millimols) was heated at 40° C. with vigorous stirring for four hours. Acetone was then added to give a one-phase system for analytical purposes, and the solution was analyzed by gas chromatography using an Apiezon column programmed from 60° to 220° C. The following relative peak areas were observed for the cyclic components:
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04156097 |
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| 出典データセット | uspto-grants-1979_05 |
|---|
| ORD ID | ord-6bc7b792bc83400f91e2a4e27b1d9525 |
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| 出典メモ | uspto-grants-1979_05 |
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