Water → HCID 21318237、化合物

HRID 263139

反応式

HRID 263139 の反応式
[C:1]([O:4][CH:5]1[CH2:9][CH2:8][CH:7]=[CH:6]1)(=O)[CH3:2].[CH:10]1(O)[CH2:15]CC[CH:12]=[CH:11]1.O>S([O-])(O)(=O)=O.C([N+](CCCC)(CCCC)CCCC)CCC.CC(C)=O>[CH:5]1([O:4][CH:1]2[CH2:12][CH2:11][CH2:10][CH:15]=[CH:2]2)[CH2:9][CH2:8][CH:7]=[CH:6]1

参加物

6

反応物 3

HCID 962WaterHCID 131982-Cyclohexen-1-OLHCID 140735Acetic acid, cyclopent-2-en-1-yl ester

生成物 1

HCID 21318237HCID 21318237、化合物

試薬・触媒・溶媒 2

HCID 94433Tetrabutylammonium hydrogen sulfate触媒HCID 180Acetone溶媒

反応条件

温度
40 °C

実験手順

A two-phase reaction mixture containing 2-cyclopentenyl acetate (0.30 g, 2.4 millimols), 2-cyclohexenol (0.50 g, 5.1 millimols), tetrabutylammonium hydrogen sulfate (0.020 g, 0.06 millimols), and water (0.25 g, 13.9 millimols) was heated at 40° C. with vigorous stirring for four hours. Acetone was then added to give a one-phase system for analytical purposes, and the solution was analyzed by gas chromatography using an Apiezon column programmed from 60° to 220° C. The following relative peak areas were observed for the cyclic components:

後処理

  1. customA two-phase reaction mixture
  2. customto give a one-phase system for analytical purposes
  3. customprogrammed from 60° to 220° C

出典と根拠

ORDレコード
ord-6bc7b792bc83400f91e2a4e27b1d9525
出典データセット
uspto-grants-1979_05
特許番号
US04156097

関連ノート

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