関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Propionitrile | HCID 7854 | — |
| 反応物 | 2-Octanone | HCID 8093 | — |
| 反応物 | Tetramethylammonium hydroxide | HCID 60966 | — |
| 反応物 | Calciumoxide | HCID 6850728 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | 2-Nonenenitrile, 2,3-dimethyl- | HCID 103749 | — |
反応手順
Into a 100 ml. flask, equipped with a magnetic stirrer, thermometer, condensor, and static nitrogen head, was placed 13.6 g. of 2-octanone, 11 g. of propionitrile, 61 g. of calcium oxide and 0.3 g. of 25% tetramethyl ammonium hydroxide in water. The mixture was held at reflux (103° C.) for 16 hours at which time gas chromatographic analysis showed 7% product nitrile relative to starting ketone.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04156690 |
|---|
| 出典データセット | uspto-grants-1979_05 |
|---|
| ORD ID | ord-526caeda957f4c6ca162f39a48ff715a |
|---|
| 出典メモ | uspto-grants-1979_05 |
|---|
