化工社化工社 化学情報印刷レポート · 研究参考用
1,2-Benzenedicarbonitrile, 4-nitro- → 4-Phenoxyphthalonitrile
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1,2-Benzenedicarbonitrile, 4-nitro- | HCID 97443 | — |
| 反応物 | Phenolate Sodium | HCID 4445035 | — |
| 溶媒 | Dimethylformamide | HCID 6228 | — |
| 生成物 | 4-Phenoxyphthalonitrile | HCID 371800 | 49% |
反応手順
The procedure of Example 35 was followed except that 1,2-dicyano-4-nitrobenzene (1.0 part) was used in place of the 1,2-dicyano-3-nitrobenzene, 1.0 parts instead of 2.79 parts of sodium phenoxide and 20 parts instead of 50 parts of dimethylformamide were used. 1,2-Dicyano-4-phenoxybenzene (0.6 parts, 49%) was obtained as a white solid, m.pt.98°-100° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05730759 |
| 出典データセット | uspto-grants-1998_03 |
| ORD ID | ord-690d3f8480e44e9f98c5d08baf524723 |
| 出典メモ | uspto-grants-1998_03 |