6-Bromo-1-hexanol → 8-Bromooctyl prop-2-enoate

反応式

FC1C(F)=CC=CC=1C1C=C[C:12]([O:15]CCCCCCOC(=O)C=C)=[CH:11][CH:10]=1.[Br:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][OH:36].BrCCCCCCO>>[C:12]([O:36][CH2:35][CH2:34][CH2:33][CH2:32][CH2:31][CH2:30][CH2:29][CH2:28][Br:27])(=[O:15])[CH:11]=[CH2:10]

参加物

反応物 3

HCID 779706-Bromo-1-hexanol

HCID 1626071-Octanol, 8-bromo-

HCID 214594982,3-Difluoro-4'-[6-(acryloyloxy)hexyloxy]biphenyl

生成物 1

HCID 138413958-Bromooctyl prop-2-enoate収率 78%

実験手順

The same procedure as in the synthesis (a) of Example 2 was repeated except that 34.7 g of 8-bromo-1-octanol were used instead of 30 g of 6-bromo-1-hexanol to give 34.1 g (Y., 78%) of 8-acryloyloxy-1-bromooctane. GC; 97%

出典と根拠

ORDレコード: ord-9b95b3613e1d4bb6b5169caa15da0157
出典データセット: uspto-grants-1997_07
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US05645760

反応ノート

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