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4-Nitrobenzyl chloride → 4-Nitrobenzyltriphenylphosphonium chloride
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 4-Nitrobenzyl chloride | HCID 7482 | — |
| 反応物 | Triphenylphosphine | HCID 11776 | — |
| 生成物 | 4-Nitrobenzyltriphenylphosphonium chloride | HCID 12000315 | — |
反応手順
A solution of 26.3 g (0.10 moles) of triphenylphosphide and 17.2 g (0.10 moles) of p-nitrobenzyl chloride in 50 ml of benezene is refluxed for 2 hours. After cooling the solid is collected and washed with benzene. Crystallization from carbon tetrachloride petroleum ether gives colorless crystals, m.p. 278°-280° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04150105 |
| 出典データセット | uspto-grants-1979_04 |
| ORD ID | ord-6e5bd4e07c044528b4ceaa1ba598509a |
| 出典メモ | uspto-grants-1979_04 |