Potassium Hydroxide → 2,11-dihydro-11-methyl-3H-s-triazolo[3,4-b][3]benzazepin-3-one
反応式
[CH3:1][CH:2]1[C:8]2[CH:9]=[CH:10][CH:11]=[CH:12][C:7]=2[CH:6]=[CH:5][N:4]2[C:13](SC)=[N:14][N:15]=[C:3]12.[OH-:18].[K+]>>[CH3:1][CH:2]1[C:8]2[CH:9]=[CH:10][CH:11]=[CH:12][C:7]=2[CH:6]=[CH:5][N:4]2[C:13](=[O:18])[NH:14][N:15]=[C:3]12参加物
3
実験手順
11-Methyl-3-methylthio-11H-s-triazolo[3,4-b][3]benzazepine was treated with potassium hydroxide and the reaction mixture was treated as described. By this procedure was obtained 2,11-dihydro-11-methyl-3H-s-triazolo[3,4-b][3]benzazepin-3-one as crystals. Pale brown needles (as recrystallized from ethanol), m.p. 119°-120° C.
後処理
- additionthe reaction mixture was treated
出典と根拠
- ORDレコード
- ord-eaa933cba8a54ad894e6426fc27382a7
- 出典データセット
- uspto-grants-1979_04
- 特許番号
- US04150139
反応ノート
読み込み中…