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m-Chloroperbenzoic acid → 11-methylene-3-methylsulfinyl-11H-s-triazolo[3,4-b][3]benzazepine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | m-Chloroperbenzoic acid | HCID 70297 | — |
| 反応物 | 11-methylene-3-methylthio-11H-s-triazolo[3,4-b][3]benzazepine | HCID 21323409 | — |
| 生成物 | 11-methylene-3-methylsulfinyl-11H-s-triazolo[3,4-b][3]benzazepine | HCID 21323367 | — |
反応手順
By a procedure similar to that of Example 17, the reaction of 11-methylene-3-methylthio-11H-s-triazolo[3,4-b][3]benzazepine with m-chloroperbenzoic acid gave 11-methylene-3-methylsulfinyl-11H-s-triazolo[3,4-b][3]benzazepine as crystals. Recrystallization from ethyl acetate yielded colorless prisms, m.p. 140°-142° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04150139 |
| 出典データセット | uspto-grants-1979_04 |
| ORD ID | ord-9ffaacf5506e43fda0f716845647efb3 |
| 出典メモ | uspto-grants-1979_04 |