Sodium Methoxide → 3-methoxy-11-phenyl-11H-s-triazolo[3,4-b][3]benzazepine

反応式

CS([C:5]1[N:14]2[C:8]([CH:9]([C:19]3[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=3)[C:10]3[CH:18]=[CH:17][CH:16]=[CH:15][C:11]=3[CH:12]=[CH:13]2)=[N:7][N:6]=1)(=O)=O.[CH3:25][O-:26].[Na+]>>[CH3:25][O:26][C:5]1[N:14]2[C:8]([CH:9]([C:19]3[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=3)[C:10]3[CH:18]=[CH:17][CH:16]=[CH:15][C:11]=3[CH:12]=[CH:13]2)=[N:7][N:6]=1

参加物

反応物 2

HCID 10942334Sodium Methoxide

HCID 213233363-methylsulfonyl-11-phenyl-11H-s-triazolo[3,4-b][3]benzazepine

生成物 1

HCID 213233983-methoxy-11-phenyl-11H-s-triazolo[3,4-b][3]benzazepine

実験手順

The reaction of 3-methylsulfonyl-11-phenyl-11H-s-triazolo[3,4-b][3]benzazepine with sodium methoxide yielded 3-methoxy-11-phenyl-11H-s-triazolo[3,4-b][3]benzazepine. Colorless prisms (as recrystallized from aqueous methanol), melting point: 183°-184° C.

出典と根拠

ORDレコード: ord-ee7069382bb34b7aa90aeb4921fb8a59
出典データセット: uspto-grants-1979_04
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04150139

反応ノート

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