Hydrochloric Acid → 5-Hydroxyindan-1,2,3-trione, monohydrate
反応式
Br[CH:2]1[C:10](=[O:11])[C:9]2[C:4](=[CH:5][CH:6]=[C:7]([OH:12])[CH:8]=2)[C:3]1=[O:13].Cl.CS(C)=[O:17]>>[OH2:11].[OH:12][C:7]1[CH:8]=[C:9]2[C:4](=[CH:5][CH:6]=1)[C:3](=[O:13])[C:2](=[O:17])[C:10]2=[O:11]参加物
4
実験手順
A solution of 0.01 mol of 2-bromo-5-hydroxyindan-1,3-dione in 10 ml dimethyl sulphoxide was heated to 80° C. for 30 minutes. 50 ml of a 1N hydrochloric acid solution was added, after which heating was continued for 30 minutes. The oily suspension obtained after cooling was extracted with ethyl ether. The organic phase was washed in water and dried over magnesium sulphate.
後処理
- temperatureafter which heating
- customThe oily suspension obtained
- temperatureafter cooling
- extractionwas extracted with ethyl ether
- washThe organic phase was washed in water
- dry with materialdried over magnesium sulphate
出典と根拠
- ORDレコード
- ord-6294ded03b0c4240b751179effe7c5e1
- 出典データセット
- uspto-grants-1997_07
- 特許番号
- US05648381
反応ノート
読み込み中…