3,5-Dichloropentan-2-one → 3-Thiocyanato-5-chloro-2-pentanone

HRID 265638

反応式

HRID 265638 の反応式
Cl[CH:2]([CH2:6][CH2:7][Cl:8])[C:3](=[O:5])[CH3:4].[C:9]([SH:11])#[N:10].N>CC(CC)=O>[S:11]([CH:2]([CH2:6][CH2:7][Cl:8])[C:3](=[O:5])[CH3:4])[C:9]#[N:10]

参加物

4

反応物 2

HCID 940323,5-Dichloropentan-2-oneHCID 13417437Amthio

生成物 1

HCID 108776933-Thiocyanato-5-chloro-2-pentanone収率 95.7%

試薬・触媒・溶媒 1

HCID 6569Methyl Ethyl Ketone溶媒

実験手順

A suspension of 7.8 g (0.05 moles) of 3,5-dichloro-2-pentanone with 3.9 g (0.051 moles) of ammonium rhodanide in 50 cm3 of methyl-ethyl-ketone is boiled for 1 hour under stirring. Then the procedure described in Example 1 is followed. 8.5 g (95.5%) of 3-thiocyanato-5-chloro-2-pentanone are obtained, which after distillation is identical in all respect with the product of Example 1.

出典と根拠

ORDレコード
ord-691d703328a6493eb1925fa44053919f
出典データセット
uspto-grants-1997_07
特許番号
US05648498

関連ノート

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