化工社化工社 化学情報印刷レポート · 研究参考用
11-Bromoundecanoic acid → Undecanoyl chloride, 11-bromo-
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 11-Bromoundecanoic acid | HCID 17812 | — |
| 反応物 | Thionyl Chloride | HCID 24386 | — |
| 溶媒 | Dichloromethane | HCID 6344 | — |
| 生成物 | Undecanoyl chloride, 11-bromo- | HCID 85202 | — |
反応手順
A solution of 11-bromoundecanoic acid (10.00 g, 37.7 mmol) dissolved in CH2Cl2 (30 mL) was slowly added to a solution of SOCl2 (7.0 mL, 94.0 mmol) in CH2Cl2 (25 mL). The mixture was refluxed for 5 h, then concentrated in vacuo to give 11-bromoundecanoyl chloride, which was used without further purification:
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05650101 |
| 出典データセット | uspto-grants-1997_07 |
| ORD ID | ord-788d43050e674b10870d83acc19291d6 |
| 出典メモ | uspto-grants-1997_07 |