Water → CID 37314

HRID 266267

反応式

HRID 266267 の反応式
Cl[P:2]1[C:7]2[CH:8]=[CH:9][CH:10]=[CH:11][C:6]=2[C:5]2[CH:12]=[CH:13][CH:14]=[CH:15][C:4]=2[O:3]1.[OH2:16]>>[O:16]=[PH:2]1[C:7]2[CH:8]=[CH:9][CH:10]=[CH:11][C:6]=2[C:5]2[CH:12]=[CH:13][CH:14]=[CH:15][C:4]=2[O:3]1

参加物

3

反応物 2

HCID 962WaterHCID 898166H-Dibenz[c,e][1,2]oxaphosphorin, 6-chloro-

生成物 1

HCID 37314CID 37314

実験手順

Another reference (German Offenlegungsschrift 27 30 371, pp. 18 and 19) describes that 6-chloro-(6H)-dibenz-oxaphosphorin at 130° C. is combined with a large amount of water, the hydrolysis is carded out, the water is distilled off under reduced pressure and the 6-oxo-dibenzoxaphosphorin is then obtained. The operation described is technically very problematical and can hardly be carried out on a large scale, since water vaporizes at 130° C. and cools the reaction mixture. It is therefore necessary to work under increased pressure if the temperature of 130° C. is to be maintained and thus uncontrolled crystallization is to be prevented, since the target compound melts significantly above the boiling point of water.

後処理

  1. customat 130° C.
  2. distillationthe water is distilled off under reduced pressure

出典と根拠

ORDレコード
ord-090eeda62bea41b787534ba5695ec87e
出典データセット
uspto-grants-1997_07
特許番号
US05650530

関連ノート

読み込み中…