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Imidazole → N-(1-Hexylheptyl)perylene-3,4-dicarboximide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Imidazole | HCID 795 | — |
| 反応物 | Water | HCID 962 | — |
| 反応物 | 3,4,9,10-Perylenetetracarboxylic dianhydride | HCID 67191 | — |
| 反応物 | Tridecan-7-amine | HCID 574991 | — |
| 反応物 | N-(2,5-Di-t-butylphenyl)perylene-3,4-dicarboximide | HCID 11081772 | — |
| 触媒 | Zinc acetate (USP) | HCID 2724192 | — |
| 生成物 | N-(1-Hexylheptyl)perylene-3,4-dicarboximide | HCID 11443487 | — |
反応手順
1.2 g (3.1 mmol) of perylene-3,4,9, 10-tetracarboxylic dianhydride, 6.2 g of imidazole, 470 mg (2.36 mmol) of 7-aminotridecane (prepared according to J. Prakt. Chem. 1980, 322, 261), 150 mg (0.68 mmol) of zinc acetate dihydrate and 3.0 ml (170 mmol) of water are heated in an autoclave (100 ml) at 190° C. for 24 h. Workup is analogous to that used in the preparation of 2b. Yield 1.25 g (27%).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05650513 |
| 出典データセット | uspto-grants-1997_07 |
| ORD ID | ord-67282756a1ef482bb6fc7c4ab8f27489 |
| 出典メモ | uspto-grants-1997_07 |