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Aminoacetaldehyde → 1-(alpha-Phenyl-o-tolyl)imidazole
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Aminoacetaldehyde | HCID 363 | — |
| 反応物 | Trimethyl orthoformate | HCID 9005 | — |
| 反応物 | 2-Benzylaniline | HCID 119805 | — |
| 触媒 | Titanium Tetrachloride | HCID 24193 | — |
| 溶媒 | 1,2-Dimethoxyethane | HCID 8071 | — |
| 生成物 | 1-(alpha-Phenyl-o-tolyl)imidazole | HCID 21497358 | — |
反応手順
In the manner given in Example 1, α-phenyl-0-toluidine is reacted first with trimethyl orthoformate; the resulting product is reacted with aminoacetaldehyde, dimethyl acetal, and the resulting product of this reaction is heated with titanium tetrachloride in monoglyme to give 1-(α-phenyl-0-tolyl)imidazole.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US03941802 |
| 出典データセット | uspto-grants-1976_03 |
| ORD ID | ord-aa4b3d1a327b410b88fda1fb97a23e75 |
| 出典メモ | uspto-grants-1976_03 |