Methyl 2'-chloro-4-biphenylylglyoxylate → 2-Chlorobiphenyl

HRID 267370

反応式

HRID 267370 の反応式
[Cl:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[C:8]1[CH:13]=[CH:12][C:11](C(=O)C(OC)=O)=[CH:10][CH:9]=1.ClC1C=CC=CC=1C1C=CC(C(=O)C(OCCC)=O)=CC=1.ClC1C=CC=CC=1C1C=CC(C(=O)C(OC(C)(C)C)=O)=CC=1.ClC1C=CC=CC=1C1C=CC(C(=O)C(OCC2C=CC=CC=2)=O)=CC=1>>[Cl:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[C:8]1[CH:9]=[CH:10][CH:11]=[CH:12][CH:13]=1

参加物

5

反応物 4

HCID 21556326Methyl 2'-chloro-4-biphenylylglyoxylateHCID 21556354t-Butyl 2'-chloro-4-biphenylylglyoxylateHCID 21556376Propyl 2'-chloro-4-biphenylylglyoxylateHCID 21556462Benzyl 2'-chloro-4-biphenylylglyoxylate

生成物 1

HCID 2492662-Chlorobiphenyl

実験手順

When ethyl oxalyl chloride in the above example is replaced with methyl oxalyl chloride, propyl oxalyl chloride, i-propyl oxalyl chloride, t-butyl oxalyl chloride, or benzyl oxalyl chloride then the product obtained is methyl 2'-chloro-4-biphenylylglyoxylate, propyl 2'-chloro-4-biphenylylglyoxylate, i-propyl 2'-chloro-4-biphenylylglyoxoylate, t-butyl 2'-chloro-4-biphenylylglyoxylate, or benzyl 2'-chloro-4-biphenylylglyoxylate.

後処理

  1. customthe product obtained

出典と根拠

ORDレコード
ord-f00bf36a7e3240f9b86ce3648a2c8c2f
出典データセット
uspto-grants-1976_03
特許番号
US03941821

関連ノート

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