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Aminoacetaldehyde → 1-(alpha-Phenyl-o-tolyl)imidazole
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Aminoacetaldehyde | HCID 363 | — |
| 反応物 | Trimethyl orthoformate | HCID 9005 | — |
| 反応物 | 2-Benzylaniline | HCID 119805 | — |
| 触媒 | Titanium Tetrachloride | HCID 24193 | — |
| 溶媒 | 1,2-Dimethoxyethane | HCID 8071 | — |
| 生成物 | 1-(alpha-Phenyl-o-tolyl)imidazole | HCID 21497358 | — |
反応手順
In the manner given in Preparation 21, α-phenyl-o-toluidine is reacted first with trimethyl orthoformate, the resulting product is reacted with aminoacetaldehyde, dimethyl acetal, and the resulting product of this reaction is heated with titanium tetrachloride in monoglyme to give 1-(α-phenyl-o-tolyl)imidazole.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US03941803 |
| 出典データセット | uspto-grants-1976_03 |
| ORD ID | ord-95c6e07595134a3592a956073228a28d |
| 出典メモ | uspto-grants-1976_03 |