5-Bromovanillin → 5-Bromo-4-[(1,5-dimethyl-hexyl)-oxy]-m-anisaldehyde

HRID 267710

反応式

HRID 267710 の反応式
Br[CH:2]([CH2:4][CH2:5][CH2:6][CH:7]([CH3:9])[CH3:8])[CH3:3].[CH3:10][O:11][C:12]1[CH:13]=[C:14]([CH:17]=[C:18]([Br:21])[C:19]=1[OH:20])[CH:15]=[O:16]>>[Br:21][C:18]1[C:19]([O:20][CH:2]([CH3:3])[CH2:4][CH2:5][CH2:6][CH:7]([CH3:9])[CH3:8])=[C:12]([O:11][CH3:10])[CH:13]=[C:14]([CH:17]=1)[CH:15]=[O:16]

参加物

3

反応物 2

HCID 180995-BromovanillinHCID 1383322-Bromo-6-methylheptane

生成物 1

HCID 214876025-Bromo-4-[(1,5-dimethyl-hexyl)-oxy]-m-anisaldehyde

実験手順

2-bromo-6-methyl-heptane was reacted with 3-methoxy-4-hydroxy-5-bromo-benzaldehyde to obtain 5-bromo-4-[(1,5-dimethyl-hexyl)-oxy]-m-anisaldehyde (boiling point = 190°-193°C/0.1 mmHg); 2-bromo-6-methyl-heptane was reacted with p-hydroxy-benzonitrile to obtain p-[(1,5-dimethyl-hexyl)-oxy]-benzonitrile (boiling point = 165°-168°C/1.0 mmHg);

出典と根拠

ORDレコード
ord-addee749c944443b9a0ac796dff5d592
出典データセット
uspto-grants-1976_03
特許番号
US03944531

関連ノート

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