化工社化工社 化学情報印刷レポート · 研究参考用
Butanal → Butanal
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Butanal | HCID 261 | — |
| 反応物 | 1-Amino-3,3,5-trimethylcyclohexyl hydroperoxide | HCID 21510183 | — |
| 生成物 | Butanal | HCID 261 | — |
| 生成物 | 3,3,5-Trimethylcyclohexanone | HCID 13398 | — |
反応手順
Butyraldehyde (28.8 g.) in petrol (100 c.c.) was cooled to below 0° and with stirring treated with 1-amino-1-hydroperoxy-3,3,5-trimethylcyclohexane (33 g.; 93% pure). When the solid had dissolved the aqueous phase was removed and the petrol solution dried with magnesium sulphate overnight at 0°. The working up as in Example 4 gave butyraldehyde, dihydroisophorone and the same peroxide (33.0 g.) b.p. 96° - 98°/0.6 mm. as in Example 4.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US03947406 |
| 出典データセット | uspto-grants-1976_03 |
| ORD ID | ord-56f3721040364bc79a96fcdf882b5025 |
| 出典メモ | uspto-grants-1976_03 |