化工社化工社 化学情報印刷レポート · 研究参考用
Butanal → Butanal
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Butanal | HCID 261 | — |
| 反応物 | Ammonia acetate | HCID 12432 | — |
| 反応物 | 1-Aminocyclohexyl hydroperoxide | HCID 19380058 | — |
| 溶媒 | Methanol | HCID 887 | — |
| 生成物 | Butanal | HCID 261 | — |
| 生成物 | Cyclohexanone | HCID 7967 | — |
反応手順
1-Aminocyclohexyl hydroperoxide (13.1 g.), butyraldehyde (7.2 g.), methanol (25 cc.) and ammonia acetate (1.0 g.) were mixed and stored at 0°C overnight. Working up as in Example 39 gave cyclohexanone and butyraldehyde, and a product (8.4 g.), b.p. 89°/0.3 mm. (peroxide equivalent, 204; pechloric acid equivalent, 206; which was identified as ##SPC37##
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US03947406 |
| 出典データセット | uspto-grants-1976_03 |
| ORD ID | ord-d71560725e124bf9937c2ce881b6cce1 |
| 出典メモ | uspto-grants-1976_03 |