p-Anisoyl chloride → 2-(4-Chlorophenyl)-3-(4-hydroxybenzoyl)benzofuran

HRID 268365ノート

反応式

HRID 268365 の反応式
ClC1C=CC(C2OC3C=CC=CC=3C=2)=CC=1.C(Cl)(=O)C1C=CC(OC)=CC=1.[Cl:28][C:29]1[CH:34]=[CH:33][C:32]([C:35]2[O:36][C:37]3[CH:53]=[CH:52][CH:51]=[CH:50][C:38]=3[C:39]=2[C:40](=[O:49])[C:41]2[CH:46]=[CH:45][C:44]([O:47]C)=[CH:43][CH:42]=2)=[CH:31][CH:30]=1>>[Cl:28][C:29]1[CH:34]=[CH:33][C:32]([C:35]2[O:36][C:37]3[CH:53]=[CH:52][CH:51]=[CH:50][C:38]=3[C:39]=2[C:40](=[O:49])[C:41]2[CH:46]=[CH:45][C:44]([OH:47])=[CH:43][CH:42]=2)=[CH:31][CH:30]=1

参加物

4

反応物 3

HCID 7477p-Anisoyl chlorideHCID 43683122-(4-Chlorophenyl)-1-benzofuranHCID 214352602-(4-Chlorophenyl)-3-(4-methoxybenzoyl)benzofuran

生成物 1

HCID 214352692-(4-Chlorophenyl)-3-(4-hydroxybenzoyl)benzofuran

実験手順

Acylation of 2-(4-chlorophenyl)benzofuran with p-anisoyl chloride followed by demethylation of the 2-(4-chlorophenyl)-3-(4-methoxybenzoyl)benzofuran thus formed by procedures described above gives 2-(4-chlorophenyl)-3-(4-hydroxybenzoyl)benzofuran.

後処理

  1. customthus formed by procedures

出典と根拠

ORDレコード
ord-574e68acb873454380dbadfee793eb74
出典データセット
uspto-grants-1976_03
特許番号
US03947470

反応ノート

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