化工社化工社 化学情報印刷レポート · 研究参考用
Sodium Hydroxide → Hydroxide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Sodium Hydroxide | HCID 14798 | — |
| 反応物 | Tin tetrachloride | HCID 24287 | — |
| 反応物 | indium(III)chloride | HCID 159675 | — |
| 触媒 | Ferrous nitrate | HCID 9815404 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | Hydroxide | HCID 961 | — |
| 生成物 | Tin tetrachloride | HCID 24287 | — |
| 生成物 | indium(III)chloride | HCID 159675 | — |
反応手順
Sodium hydroxide (0.75 mol) was dissolved in water (180 ml) to prepare an aqueous alkaline solution. Separately from this alkaline solution, an aqueous solution of tin chloride and indium chloride was prepared by dissolving indium chloride (III) tetrahydrate (0.067 mol) and tin chloride (IV) pentahydrate (0.007 mol) in water (400 ml). To the former aqueous alkaline solution, was added dropwise the latter aqueous solution of tin chloride and indium chloride to form a precipitate of a hydroxide or a hydrate comprising tin and indium. The pH of the precipitate was 10.2. A suspension of the precipitate was aged at room temperature for 20 hours, and then washed with water until the pH of the precipitate reached 7.6.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07445858B2 |
| 出典データセット | uspto-grants-2008_11 |
| ORD ID | ord-ab1889d9a37a4eda82d1adf42c4ef737 |
| 出典メモ | uspto-grants-2008_11 |