化工社化工社 化学情報印刷レポート · 研究参考用
Triethylamine → (Z,E,E)-N-ethyl-7-hydroxymethyl-3,11,15-trimethyl-2,6,10,14-hexadecatetraenamide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Triethylamine | HCID 8471 | — |
| 反応物 | Ethylamine hydrochloride | HCID 11198 | — |
| 反応物 | (Z,E,E)-7-hydroxymethyl-3,11,15-trimethyl-2,6,10,14-hexadecatetraenoic acid | HCID 86736493 | — |
| 溶媒 | Dimethylformamide | HCID 6228 | — |
| 生成物 | (Z,E,E)-N-ethyl-7-hydroxymethyl-3,11,15-trimethyl-2,6,10,14-hexadecatetraenamide | HCID 86736492 | — |
反応手順
Following the same manner as in Example 9, the reaction and after-treatment were conducted by using 1.1 g of (E,Z,E), (E,E,E), (Z,Z,E) and (Z,E,E)-7-hydroxymethyl-3,11,15-trimethyl-2,6,10,14-hexadecatetraenoic acid, 350 mg of ethylamine hydrochloride, 0.80 ml of diphenylphosphoric acid azide and 1.0 ml of triethylamine in 6.0 ml of N,N-dimethylformamide to afford 780 mg of the end product.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04151357 |
| 出典データセット | uspto-grants-1979_04 |
| ORD ID | ord-fcc0677d475e4811b987e8238c97049a |
| 出典メモ | uspto-grants-1979_04 |