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Trichlorosilane → 13-Tetradecenyl trichlorosilane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Trichlorosilane | HCID 24811 | — |
| 反応物 | Tetradeca-1,13-diene | HCID 30875 | — |
| 触媒 | Mercury | HCID 23931 | — |
| 生成物 | 13-Tetradecenyl trichlorosilane | HCID 10131540 | 30.3% |
反応手順
A stirred mixture of 6.8 g (0.05 mole) trichlorosilane and 19.6 g (0.1 mole) 1,13-tetradecadiene was irradiated in a closed quartz tube at 45° C. for 72 hours with two Hanau 70 watt high pressure mercury immersion lamps, emitting a broad spectrum of ultraviolet light. The resulting crude product was then fractionated to yield 5 g (25%) of 13-tetradecenyl trichlorosilane as the monoadduct.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04220556 |
| 出典データセット | uspto-grants-1980_09 |
| ORD ID | ord-8e527906fad14278b2fcf42dbc64f754 |
| 出典メモ | uspto-grants-1980_09 |