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Water → N-(((2,6-Dichlorophenyl)amino)thioxomethyl)benzamide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Water | HCID 962 | — |
| 反応物 | Benzyl Chloride | HCID 7503 | — |
| 反応物 | 2,6-Dichloroaniline | HCID 11846 | — |
| 反応物 | Ammonium thiocyanate | HCID 15666 | — |
| 溶媒 | Acetone | HCID 180 | — |
| 生成物 | N-(((2,6-Dichlorophenyl)amino)thioxomethyl)benzamide | HCID 702451 | — |
反応手順
To 51.8 g (0.68 mole) of ammonium thiocyanate in 300 ml acetone is added 86.8 g (0.62 mole) of benzyl chloride. The reaction mixture is refluxed for about 5 min. and then 100 g (0.62 mole) of 2,6-dichloroaniline in 200 ml acetone is added at a rate to maintain reflux. The mixture is refluxed for 11/2 hours, cooled, poured into 11/2 liters of ice and water, filtered to obtain 1-(2,6-dichlorophenyl)-3-benzoylthiourea.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04220658 |
| 出典データセット | uspto-grants-1980_09 |
| ORD ID | ord-ee423d099bfc46fcb321850ee7ca0ec7 |
| 出典メモ | uspto-grants-1980_09 |