Performic Acid → 2-(3-Methylsulfinylphenyl)-2,4,5,6-tetrahydro-1,3,4,6,6-pentamethylcyclopenta[c]pyrrole-4-carboxamide

HRID 27214

反応式

HRID 27214 の反応式
[CH3:1][S:2][C:3]1[CH:4]=[C:5]([N:9]2[C:13]([CH3:14])=[C:12]3[C:15]([CH3:23])([C:20]([NH2:22])=[O:21])[CH2:16][C:17]([CH3:19])([CH3:18])[C:11]3=[C:10]2[CH3:24])[CH:6]=[CH:7][CH:8]=1.C(OO)=[O:26]>CC(C)=O>[CH3:1][S:2]([C:3]1[CH:4]=[C:5]([N:9]2[C:13]([CH3:14])=[C:12]3[C:15]([CH3:23])([C:20]([NH2:22])=[O:21])[CH2:16][C:17]([CH3:19])([CH3:18])[C:11]3=[C:10]2[CH3:24])[CH:6]=[CH:7][CH:8]=1)=[O:26]

参加物

4

反応物 2

HCID 66051Performic AcidHCID 203205762-(3-Methylmercaptophenyl)-2,4,5,6-tetrahydro-1,3,4,6,6-pentamethylcyclopenta[c]pyrrole-4-carboxamide

生成物 1

HCID 234561822-(3-Methylsulfinylphenyl)-2,4,5,6-tetrahydro-1,3,4,6,6-pentamethylcyclopenta[c]pyrrole-4-carboxamide

試薬・触媒・溶媒 1

HCID 180Acetone溶媒

実験手順

Reaction of the 2-(3-methylmercaptophenyl)-2,4,5,6-tetrahydro-1,3,4,6,6-pentamethylcyclopenta[c]pyrrole-4-carboxamide described above in Example 1CK with one molar equivalent of performic acid in acetone at room temperature affords 2-(3-methylsulfinylphenyl)-2,4,5,6-tetrahydro-1,3,4,6,6-pentamethylcyclopenta [c]pyrrole-4-carboxamide.

出典と根拠

ORDレコード
ord-af5d2e0adbe948db97d9987e95e69681
出典データセット
uspto-grants-1980_09
特許番号
US04220763

関連ノート

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