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Acifluorfen → t-Octylammonium 5-(2-Chloro-4-trifluoromethylphenoxy)-2-nitrobenzoate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Acifluorfen | HCID 44073 | — |
| 反応物 | tert-Octylamine | HCID 61017 | — |
| 溶媒 | 1,2-Dimethoxyethane | HCID 8071 | — |
| 生成物 | t-Octylammonium 5-(2-Chloro-4-trifluoromethylphenoxy)-2-nitrobenzoate | HCID 21280025 | 68.7% |
反応手順
5-(2-Chloro-4-trifluoromethylphenoxy)-2-nitrobenzoic acid (3.0 g, 0.0083 mole) is dissolved in glyme (20 ml) and t-octylamine (1.17 g, 0.0091 mole) is added rapidly while stirring. The solvent is removed in vacuo and the residue triturated with petroleum either (bp 30°-60° C.) and dried to give 2.8 g of product, mp 140°-57° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04220468 |
| 出典データセット | uspto-grants-1980_09 |
| ORD ID | ord-884dca2509ea4a878eebbc80f47f85a6 |
| 出典メモ | uspto-grants-1980_09 |