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Benzyl Chloride → Benzyl Phenyl Ether
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Benzyl Chloride | HCID 7503 | — |
| 反応物 | Sodium Phenoxide Trihydrate | HCID 23681143 | — |
| 溶媒 | Methanol | HCID 887 | — |
| 生成物 | Benzyl Phenyl Ether | HCID 70352 | 67% |
反応手順
A mixture of sodium phenolate trihydrate (10.2 g; 60 mmole) and benzyl chloride (6.4 ml; 56 mmole) in methanol (150 ml) was pumped through the system (15 ml/minute; 146°-7° C.; 1000-1050 kPa). The MeOH was rotary evaporated off and the residue recrystallised from EtOH to afford colourless needles of phenyl benzyl ether (6.9 g; 67% yield), m.p. 36°-36.3° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05387397 |
| 出典データセット | uspto-grants-1995_02 |
| ORD ID | ord-80ea20519fd44352987956fe78cc4b12 |
| 出典メモ | uspto-grants-1995_02 |