関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Triphenylphosphine | HCID 11776 | — |
| 反応物 | Benzene, (3-chloro-1-propenyl)- | HCID 94242 | — |
| 溶媒 | O-Xylene | HCID 7237 | — |
| 生成物 | [(E)-cinnamyl]-triphenyl-phosphonium chloride | HCID 73729 | — |
反応手順
88.2 parts of triphenylphosphine was dissolved in 240 parts of xylene and 51.3 parts of cinnamyl chloride was added thereto. The mixture was heated at 130° C. for 4 hr. After the mixture was cooled to 30° C., the resulting colorless crystals were collected by filtration and washed with toluene to obtain 117.4 parts of cinnamyltriphenylphosphonium chloride (compound No. 15).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US05389486 |
|---|
| 出典データセット | uspto-grants-1995_02 |
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| ORD ID | ord-fa939c3d200942e0a4f0c4e26a59ee5a |
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| 出典メモ | uspto-grants-1995_02 |
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