[(E)-cinnamyl]-triphenyl-phosphonium chloride → Cinnamyltriphenylphosphonium tetrafluoroborate

HRID 274194

反応式

HRID 274194 の反応式
[Cl-].[CH2:2]([P+:11]([C:24]1[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1)([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[CH:3]=[CH:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1.[F:30][B-:31]([F:34])([F:33])[F:32].[Na+]>O>[F:30][B-:31]([F:34])([F:33])[F:32].[CH2:2]([P+:11]([C:24]1[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1)([C:12]1[CH:13]=[CH:14][CH:15]=[CH:16][CH:17]=1)[C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)[CH:3]=[CH:4][C:5]1[CH:6]=[CH:7][CH:8]=[CH:9][CH:10]=1

参加物

4

反応物 2

HCID 73729[(E)-cinnamyl]-triphenyl-phosphonium chlorideHCID 4343483Sodium Tetrafluoroborate

生成物 1

HCID 72739364Cinnamyltriphenylphosphonium tetrafluoroborate

試薬・触媒・溶媒 1

HCID 962Water溶媒2 回

実験手順

10.4 parts of cinnamyltriphenylphosphonium chloride prepared in the above Synthetic Example 2 was dissolved in 580 parts of water and a solution of 2.7 parts of sodium tetrafluoroborate in 9 parts of water was slowly added dropwise thereto. After 6 hr stirring, the resulting colorless crystals were collected by filtration, washed with 300 parts of water, and dried to obtain 10.1 parts of cinnamyltriphenylphosphonium tetrafluoroborate (compound No. 5).

後処理

  1. filtrationthe resulting colorless crystals were collected by filtration
  2. washwashed with 300 parts of water
  3. customdried

出典と根拠

ORDレコード
ord-67f66f067c0c4272bda2b0c3e13dbf7f
出典データセット
uspto-grants-1995_02
特許番号
US05389486

関連ノート

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