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2-Aminophenol → 2H-1,4-Benzoxazin-2-one, 3-(3,4-dihydroxy-5-nitrophenyl)-
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 2-Aminophenol | HCID 5801 | — |
| 反応物 | Benzeneacetic acid, 3,4-dihydroxy-5-nitro-alpha-oxo-, hexyl ester | HCID 5747978 | — |
| 生成物 | 2H-1,4-Benzoxazin-2-one, 3-(3,4-dihydroxy-5-nitrophenyl)- | HCID 135624032 | — |
反応手順
A mixture of 3.93 g of n-hexyl 3,4-dihydroxy-5-nitrophenylglyoxylate and 1.38 g of 2-aminophenol is melted at 120° while stirring. The melt crystallizes after 5 minutes. After 2 hours it is cooled and recrystallized from methanol. There is obtained 3-(3,4-dihydroxy-5-nitrophenyl)-2H-1,4-benzoxazin-2-one of m.p. 202°-204°.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05389653 |
| 出典データセット | uspto-grants-1995_02 |
| ORD ID | ord-bc5bc0963fd1411a9ee7e24a001c9c6f |
| 出典メモ | uspto-grants-1995_02 |