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O-Phenylenediamine → 2(1H)-Quinoxalinone, 3-(3,4-dihydroxy-5-nitrophenyl)-
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | O-Phenylenediamine | HCID 7243 | — |
| 反応物 | Benzeneacetic acid, 3,4-dihydroxy-5-nitro-alpha-oxo-, hexyl ester | HCID 5747978 | — |
| 溶媒 | Methanol | HCID 887 | — |
| 生成物 | 2(1H)-Quinoxalinone, 3-(3,4-dihydroxy-5-nitrophenyl)- | HCID 135665317 | — |
反応手順
A mixture of 396.0 mg of n-hexyl 3,4-dihydroxy-5-nitrophenylglyoxylate and 137.6 mg of 1,2-phenylenediamine is heated to 120° for 60 minutes. Thereafter, the mixture is suspended in methanol, filtered under suction and recrystallized from N,N-dimethylformamide/water. There is obtained 3-(3,4-dihydroxy-5-nitrophenyl)-2(1H)-quinoxalinone of m.p. >300°.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05389653 |
| 出典データセット | uspto-grants-1995_02 |
| ORD ID | ord-c245f17d7eed4973844b162fb366d595 |
| 出典メモ | uspto-grants-1995_02 |