Acetic Anhydride → 2-(4-Carboxybenzamido)-4-acetamidobenzoic acid

HRID 27471ノート

反応式

HRID 27471 の反応式
[C:1]([C:4]1[CH:22]=[CH:21][C:7]([C:8]([NH:10][C:11]2[CH:19]=[C:18]([NH2:20])[CH:17]=[CH:16][C:12]=2[C:13]([OH:15])=[O:14])=[O:9])=[CH:6][CH:5]=1)([OH:3])=[O:2].[C:23](OC(=O)C)(=[O:25])[CH3:24]>>[C:1]([C:4]1[CH:5]=[CH:6][C:7]([C:8]([NH:10][C:11]2[CH:19]=[C:18]([NH:20][C:23](=[O:25])[CH3:24])[CH:17]=[CH:16][C:12]=2[C:13]([OH:15])=[O:14])=[O:9])=[CH:21][CH:22]=1)([OH:3])=[O:2]

参加物

3

反応物 2

HCID 7918Acetic AnhydrideHCID 233430382-(4-Carboxybenzamido)-4-aminobenzoic acid

生成物 1

HCID 233430402-(4-Carboxybenzamido)-4-acetamidobenzoic acid収率 63%

実験手順

The procedure of Example 4 was repeated to react 2-(4-carboxybenzamido)-4-aminobenzoic acid with acetic anhydride, and the reaction product was treated as in Example 4 to yield 63% of 2-(4-carboxybenzamido)-4-acetamidobenzoic acid having a melting point in the range of from 302° to 304° C. (decompose).

後処理

  1. additionthe reaction product was treated as in Example 4

出典と根拠

ORDレコード
ord-c5a34530c1b6401a99fdc28327f2a46b
出典データセット
uspto-grants-1980_09
特許番号
US04221814

反応ノート

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