化工社化工社 化学情報印刷レポート · 研究参考用
Triethyl Citrate → Ethyl tetrahydrofurfurylacetate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Triethyl Citrate | HCID 6506 | — |
| 反応物 | Tetrahydrofuran | HCID 8028 | — |
| 反応物 | HCID 178418361 | HCID 178418361 | — |
| 生成物 | Ethyl tetrahydrofurfurylacetate | HCID 263175 | 39% |
| 生成物 | 2-(Oxolan-3-yl)ethan-1-ol | HCID 11126225 | 30% |
反応手順
400 ml of triethyl citrate were hydrogenated at 175° C. and 50 bar together with 1100 ml of tetrahydrofuran and 60 g of catalyst F (4-mm tablets) until the take-up of hydrogen had ceased. The reaction product was freed from tetrahydrofuran and distilled under reduced pressure, giving 101 g (39%) of ethyl tetrahydrofurfurylacetate and 57 g (30%) of 3-(2'-hydroxyethyl)tetrahydrofuran.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05391771 |
| 出典データセット | uspto-grants-1995_02 |
| ORD ID | ord-b5ff5c4a485e45258089b7c7e10d1743 |
| 出典メモ | uspto-grants-1995_02 |